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Jesse James and Kat Von D hit the red carpet last night at the Beverly Hilton Hotel for the prestigious event, An Evening With Women 2011. Dare we suggest that despite his signature far-off stare, they were a decidedly striking couple.

James, 41, and actress Sandra Bullock ended their marriage in 2010. Kat, his future bride, is a 29-year-old tattoo artist and television personality. They confirmed in January that they are engaged — sparkler pic here.

The fundraiser for women-specific services at the L.A. Gay & Lesbian Center drew a celebrity crowd. Performers included Cyndi Lauper, Cat Power, Juliette Lewis and Sarah Silverman.

Newly-engaged couple Chely Wright and Lauren Blizer obliged photographers by kissing for the camera.

More photos below:

Photos: FayesVision-WENN